The policy of excluding negligibly reactive compounds from the regulatory definition of VOC was first laid out in the “Recommended Policy on Control of Volatile Organic Compounds” (42 FR 35314, July 8, 1977) and was supplemented subsequently with the “Interim Guidance on Control of Volatile Organic Compounds in Ozone State Implementation Plans”. LVP exclusion If a substance qualifies for LVP exclusion, it is not counted as a VOC and VOC limits do not apply to its use for most product categories regulated under Consumer Product Rules. Note that EPA will only exempt pure compounds. United States Environmental Protection Agency. CARB conducted further research to better understand impacts of LVP-VOCs emitted from the use of consumer products on ozone and secondary organic aerosol formation, and their environmental fate. VOC Content and VOC Exemption Rules Many states defer to the South Coast Air Quality Management District of California (the air pollution regulator for the Los Angeles basin) for VOC content limits. ANGUS submitted a VOC-exemption petition to the EPA in October 2012 after tests performed at an independent lab confirmed that AMP meets or exceeds the agency’s no-VOC benchmarks. EPA’s Safer Choice Criteria for VOC -exempt Solvents EPA’s Safer Choice Program will allow the use of certain solvents that do not fully comply with the Safer Choice Criteria for Solvents (at http://www2.epa.gov/saferchoice/standard) in specific circumstances. PC is a less aggressive solvent in certain I&I applications, but it is highly miscible and can be used in customized blends (i.e. This action will allow states to remove regulatory controls on AMP that are part of State Implementation Plans designed to help meet the ground-level ozone standards. : Propylene Carbonate is exempted as a low reactivity compound by the EPA and also qualifies for the LVP-VOC exemption. EPA does not review or issue notices of exemption for products which meet the conditions for exemption. VOC-Exempt Solvents EPA regulations include a list of compounds that are explicitly exempted from regulation as VOCs, even though they are “compounds of carbon.” These include a short list of compounds such as carbon monoxide and carbon dioxide that historically have not been regulated as VOCs, and a longer list of compounds that EPA has classified as “negligibly reactive.” U.S. EPA grants AMP VOC-exempt status In 2015, the United States Environmental Protection Agency (EPA) revised its regulatory definition to remove AMP from being regulated as a VOC, allowing the product to support an environmentally conscious domestic market. Since 1977, EPA has with DMEs). Interim Guidance on Control of Volatile Organic Compounds in Ozone State Implementation Plans, SIP Training Presentations and Assistance. … Update: U.S. EPA Exempt Volatile Organic Compounds PAINT -The U.S. Environmental Protection Agency (EPA) has determined that certain volatile organic compounds (VOC) have been determined to have negligible photochemical reactivity (40 CFR 51.100 (s)). Outdoors, VOCs are volatized or released into the air mostly during manufacture or use of everyday products and materials. This table shows how each list refers to the substance. Contact Us to ask a question, provide feedback, or report a problem. EPA defines a VOC as “any compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, which participates in atmospheric photochemical reactions,” with the exception of chemicals that EPA has determined to have “negligible photochemical reactivity,” such as 2-amino-2-methyl-1-propanol. Complete list of VOC Exemption Rules Jump to main content An official website of the United States government. In the summer of 2014, the United States Environmental Protection Agency (EPA) revised its regulatory definition to remove AMP from being regulated as a volatile organic compound (VOC) according to the U.S. Clean Air Act on the basis that AMP makes a negligible contribution to tropospheric (ground-level) ozone formation. AMP is used in a variety of applications for pigment dispersion in water-based coatings suc… To view more metadata about Indoors, VOCs are mostly released into the air from the use of products and materials containing VOCs.VOCs are of concern as both indoor air pollutants and as outdoor air pollutants. https://www.govinfo.gov/content/pkg/FR-1977-07-08/pdf/FR-1977-07-08.pdf#page=148, 1,1,1 trichloroethane (methyl chloroform), Air Quality- Recommended policy on control of VOC, https://www.govinfo.gov/content/pkg/FR-1979-06-04/pdf/FR-1979-06-04.pdf#page=112, Clarification on dichloromethane (methylene chloride and/or methyl chloroform), https://www.govinfo.gov/content/pkg/FR-1980-05-16/pdf/FR-1980-05-16.pdf#page=146, https://www.govinfo.gov/content/pkg/FR-1980-07-22/pdf/FR-1980-07-22.pdf#page=103, 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113)- Trichlorotrifluoroethane, 1,2-dichloro-1,1,2,2-tetrafluoroethane (CFC-114), 1,1,1-trifluoro-2,2-dichloroethane (HCFC-123), https://www.govinfo.gov/content/pkg/FR-1989-01-18/pdf/FR-1989-01-18.pdf#page=71, 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), https://www.govinfo.gov/content/pkg/FR-1991-03-18/pdf/FR-1991-03-18.pdf#page=80. Note that EPA will only exempt pure compounds. Volatile Organic Compounds (VOC's) react with nitrogen oxides on hot summer days to form ozone (smog). On May 30, 2017, Illinois submitted, as a SIP revision, a change to the definition of VOC at 35 IAC 211.7150 in response to an EPA rulemaking in 2016 that updated an existing exemption for the compound tertiary butyl acetate EPA Applications/Systems Below are the EPA applications/systems, statutes/regulations, or other sources that track or regulate this substance. Propylene Carbonate (also specifically exempted by EPA): Propylene Carbonate is exempted as a low reactivity compound by the EPA and also qualifies for the LVP-VOC exemption. The U.S. EPA definition is VOCs that have a vapor pressure < 0.1 mmHg at 20 C or a melting point > 20 C and does not sublime, if the vapor pressure is not known. with DMEs). The EPA lists compounds that it has determined to be negligibly reactive in its regulations as being excluded from the regulatory definition of VOCs (40 CFR 51.100 (s)), i.e., these are considered to make a negligible contribution to ground-level ozone formation. On October 17, 2011 and February 15, 2013, the U.S. EPA also proposed to add the following two compounds to the list of exclusions from their VOC definition:  2,3,3,3-tetrafluoropropene (HFO-1234yf)15 trans 1-chloro-3,3,3-trifluoroprop-1-ene (SolsticeTM1233zd(E))16 The U.S. EPA decision is still pending for these two compounds. Those VOCs, determined to have low photochemical reactivity by approved test methods, may be excluded as VOC for regulatory purposes. As you are aware, the Federal EPA has exempted these two solvents from the definition of VOC. On August 13, 2020, EPA released its final rules rolling back standards to control methane and VOC emissions from new oil and gas facilities. Those VOCs, determined to have low photochemical reactivity by approved test methods, may be excluded as VOC for regulatory purposes. The regulatory definition of VOC, including those compounds determined to have neglible photochemical reactivity,  has been pubished in the Code of Federal Regulations Part 51.100. 2. An official website of the United States government. VOC Exemption Story In the U.S., a compound may be excluded as a VOC as a result of public petitions and new scientific data that demonstrate its negligible effect on the formation of ground-level ozone. However, SCAQMD Rule 102 includes VOC-exempt products which may or may not be listed as VOC-exempt by the EPA. The U.S. Environmental Protection Agency (EPA) has determined that certain volatile organic compounds (VOC) have been determined to have negligible photochemical reactivity ( 40 CFR 51.100 (s) ). There are thousands of individual chemical species of VOCs that can react to form ozone. VOC exempt solvents are organic compounds that are exempt from restrictions placed on most volatile organic compounds (VOCs) in the United States. Evidence shows that AMP is negligibly reactive in forming ground-level ozone. The two rules were published in the Federal Register on September 14th and 15th , 2020. Car exhaust, gasoline-powered lawn and garden equipment, gasoline dispensing stations, industrial coating operations, printing shops, paints, household chemicals - are some of the sources of VOC. These determinations are made by regulation and are commonly referred to as VOC Exemptions. The EPA has also determined that exemption of HFO-1336mzz-Z from the regulatory definition of VOC will not result in an increase of risk to human health and the environment, and, to the extent that use of this compound does These determinations are made by regulation and are commonly referred to as VOC Exemptions. She leads the VOC exemption program and related rule making for the revision of the EPA’s regulatory definition of VOC heading a workgroup of experts on HAPs among other toxic pollutants. Federal Register references on that exemption are: 42 FR 35314 of … The United States Environmental Protection Agency (U.S. EPA) excludes certain organic compounds from the regulatory definition of a VOC based on the compound's negligible contribution to the formation of ground-level ozone, better known as smog. The definition for volatile organic compounds (VOC) comes from the Order adding toxic substances to Schedule 1 to the Canadian Environmental Protection Act, 1999, section 1, published in the Canada Gazette, Part II, July 2, 2003 and its amendment published June 3, 2016. Ground Level Ozone. 1. The most recent list of VOC Exemptions are available here. March 27, 2014 - EPA added 2-Amino-2-methyl-1-propanol (also known as AMP, CAS124-68-5) to the list of compounds excluded from the regulatory definition of VOC. Smog is formed when VOCs photochemically react with oxides of nitrogen (NOx) in the atmosphere. Some VOCs react slowly and changes in their emissions have limited effects on local or regional ozone pollution episodes. cyclic, branched, or linear, completely fluorinated alkanes; cyclic, branched, or linear, completely fluorinated ethers with no unsaturations; cyclic, branched, or linear, completely fluorinated tertiary amines with no unsaturations; and, sulfur containing perfluorocarbons with no unsaturations and with sulfur bonds only to carbon and fluorine, https://www.govinfo.gov/content/pkg/FR-1994-10-05/pdf/FR-1994-10-05.pdf#page=25, cyclic, branched, or linear completely methylated siloxanes, https://www.govinfo.gov/content/pkg/FR-1995-06-16/pdf/95-14804.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-1996-02-07/pdf/96-2495.pdf#page=2, 3,3-dichloro-1,1,1,2,2-pentafluoropropane (HCFC-225ca), https://www.govinfo.gov/content/pkg/FR-1996-10-08/pdf/96-25787.pdf#page=1, 1,3-dichloro-1,1,2,2,3-pentafluoropropane (HCFC-225cb), 1,1,1,2,3,4,4,5,5,5-decafluoropentane (HFC-43-10mee), https://www.govinfo.gov/content/pkg/FR-1997-08-25/pdf/97-22510.pdf#page=1, 1,1,1,3,3,3-hexafluoropropane (HFC-236fa), 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a), 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-butane (C4F9OCH3), 2-(difluoromethoxymethyl)-1,1,1,2,3,3,3-heptafluoropropane ((CF3)2CFCF2OCH3), 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane (C4F9OCH2H5), 2-(ethoxydifluoromethyl)-1,1,1,2,3,3,3-heptafluoropropane ((CF3)2CFCF2OC2H5), https://www.govinfo.gov/content/pkg/FR-1998-04-09/pdf/98-9247.pdf#page=1, 1,1,1,2,2,3,3- heptafluoro-3-methoxy-propane (n-C3F7OCH3  or HFE-7000), https://www.govinfo.gov/content/pkg/FR-2004-11-29/pdf/04-26070.pdf#page=1, 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-(trifluoromethyl) hexane (HFE-7500), 1,1,1,2,3,3,3-hetafluoropropane (HFC-227ea), https://www.govinfo.gov/content/pkg/FR-2004-11-29/pdf/04-26069.pdf#page=1, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-trifluoromethyl-pentane (also known as HFE-7300), https://www.govinfo.gov/content/pkg/FR-2007-01-18/pdf/E7-638.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2009-01-21/pdf/E9-1150.pdf#page=1, trans-1,3,3,3-tetrafluoropropene (HFO-1234ze), https://www.govinfo.gov/content/pkg/FR-2012-06-22/pdf/2012-15347.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2013-02-12/pdf/2013-03057.pdf#page=1, HCF2OCF2OCF2CF2OCF2H (H-Galden 1040X, ZT 130, 150, or 180), trans-1-chloro-3,3,3-trifluoroprop-1-ene (SolsticeTM 1233zd(E)), https://www.govinfo.gov/content/pkg/FR-2013-08-28/pdf/2013-21014.pdf#page=1, 2,3,3,3-tetrafluoropropene   (HFO-1234yf), https://www.govinfo.gov/content/pkg/FR-2013-10-22/pdf/2013-23783.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2014-03-27/pdf/2014-06790.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2016-02-25/pdf/2016-04072.pdf#page=1, 1,1,2,2-Tetrafluoro-1-(2,2,2-trifluoroethoxy) ethane (HFE-347pcf2), https://www.govinfo.gov/content/pkg/FR-2016-08-01/pdf/2016-17790.pdf#page=1, 1,1,1,4,4,4-hexafluorobut-2-ene (HFO-1336mzz-Z), https://www.govinfo.gov/content/pkg/FR-2018-11-28/pdf/2018-25891.pdf#page=1. Car exhaust, gasoline-powered lawn and garden equipment, gasoline dispensing stations, industrial coating operations, printing shops, paints, household chemicals - are some of the sources of VOC. Contact Us to ask a question, provide feedback, or report a problem. An official website of the United States government. Organic chemical compounds1 are everywhere in both indoor and outdoor environments because they have become essential ingredients in many products and materials. This exemption was designed to prioritize reductions in VOC compounds that most readily participate in ozone formation. Ozone Volatile Organic Compounds (VOC) Exemptions Fact Sheets This page contains fact sheets on EPA rulings removing certain chemical compounds from being regulation as volatile organic compounds (VOC) under the Clean Air Act. PC is a less aggressive solvent in certain I&I applications, but it is highly miscible and can be used in customized blends (i.e. In October 2012 ANGUS submitted a petition to the EPA to exempt AMP from regulation as a VOC. Federal Register references on that exemption are: Federal Register references on that exemption are: 42 FR 35314 of July 8, 1977 It has been the EPA’s policy that organic compounds with a negligible level of reactivity should be excluded from the regulatory VOC definition so as to focus VOC control efforts on compounds that do significantly increase ozone concentrations. United States Environmental Protection Agency. As you are aware, the Federal EPA has exempted these two solvents from the definition of VOC. Sale or distribution of a pesticide product meeting all the criteria m 40 CFR 152.25(g) without a federal registeation is not a violation of FIFRA. 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